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Carbapenems epimerization

Base-catalysed epimerization at the benzylic pyrrolidine C(2) position of a new carbapenem is induced by a remote cationic centre,163 and irreversible photodeprotona-... [Pg.350]

The p-lactam ring is formed by an acyl-adenosine monophosphate ester. The 2-oxoglutarate-dependent oxygenase enzyme, carbapenems synthase, dehydrogenates the pyrroHdine ring and also epimerizes the fused ring at position 5. However, the mechanism involved in this conversion is not yet clear [116]. [Pg.134]

See other pages where Carbapenems epimerization is mentioned: [Pg.10]    [Pg.406]    [Pg.82]    [Pg.10]    [Pg.573]    [Pg.620]    [Pg.621]    [Pg.649]    [Pg.309]    [Pg.310]    [Pg.134]   
See also in sourсe #XX -- [ Pg.350 ]

See also in sourсe #XX -- [ Pg.350 ]

See also in sourсe #XX -- [ Pg.350 ]



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Carbapenem

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