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Cage effect, matrix isolation radicals

The cage effect can be a source of great frustration in matrix isolation studies of monoradicals, because such species are usually formed by homolysis from closed-shell compounds, and hence any radical generated in situ is invariably accompanied by another radical that will be trapped in the same matrix cage. [Pg.816]


See other pages where Cage effect, matrix isolation radicals is mentioned: [Pg.308]    [Pg.37]    [Pg.114]    [Pg.3]    [Pg.310]    [Pg.21]    [Pg.57]    [Pg.149]    [Pg.331]   
See also in sourсe #XX -- [ Pg.816 , Pg.817 ]




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