Buffers alpha plots

An alpha plot for a buffer (or an amino acid) shows the percentage of each component in a buffer system as a function of pH. Alpha for a given species is the percent of all the material that is present in that form. So, when alpha for the conjugate acid form is 75%, the ratio of conjugate acid to conjugate base is 75 25. Naturally, the sum of the alpha values for the conjugate acid and the conjugate base add up to 100%. 

The shape of the curves in an alpha plot is determined by the buffer equation. At low pH, most of the material is present as its conjugate acid. As the pH increases, the conjugate acid form converts to the conjugate base form. At high pH, most of the material is present in the conjugate base form. 

Calculating the pH of a Buffer 248 Dilution of Buffer Solutions 251 Buffer Capacity 251 Alpha Plots 252... 

The composition of buffer solutions can be visualized by plotting the relative equilibrium concentrations of the two components of a conjugate acid/base as a function of the pH of the solution. These relative concentrations are called alpha values. For example, if we let be the sum of the analytical concentrations of acetic acid and sodium acetate in a typical buffer solution, we may write... 

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