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Brutto-equation and the number of steps

Every graph s cycle corresponds to its natural brutto-equation. We will assume that the stoichiometric coefficients in this equation are minimum integer-valued, i.e. for simplicity the multiplicity is taken to be equal to unity (see Sects. 2.3 and 2.4). We suggest that, as in all the above examples, only one molecule of each observed substance (either initial or product) is either consumed or formed. [Pg.244]

for a mechanism of class 1, one can give a simple estimate of the number of steps corresponding to a given brutto-equation [Pg.244]

Let us apply estimate (94) to the various mechanisms of class 1 given above. For the Michaelis-Menten mechanism, the brutto-reaction is of the form S = P, nln = 1, nprod = 1, and s = 1 + 1 = 2. For CO conversion, the brutto-equation takes the form [Pg.244]

In the two-route mechanism of vinyl chloride synthesis, the number of [Pg.244]

Thus eqn. (94) is fulfilled in the mechanisms considered as an accurate estimate for the number of steps. More often it is a lower bound (according to the number of molecules either of the initial substances or of products) and rarely will it be an upper bound (according to the number of the initial substances and products). [Pg.245]


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BRUTTO

Equations numbering

Number of Steps

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