Brownian motion diffusion equation with fractional

The main objective of this chapter is to establish the relation between the macroscopic equations like (3.1) and (3.5), the mesoscopic equations (3.2) and (3.3), etc., and the underlying microscopic movement of particles. We will show how to derive mesoscopic reaction-transport equations like (3.2) and (3.3) from microscopic random walk models. In particular, we will discuss the scaling procedures that lead to macroscopic reaction-transport equations. As an example, let us mention that the macroscopic reaction-diffusion equation (3.1) occurs as a result of the convergence of the random microscopic movement of particles to Brownian motion, while the macroscopic fractional equation (3.5) is closely related to the convergence of random walks with heavy-tailed jump PDFs to a-stable random processes or Levy flights. 

The Peclet number compares the effect of imposed shear (known as the convective effect) with the effect of diffusion of the particles. The imposed shear has the effect of altering the local distribution of the particles, whereas the diffusion (or Brownian motion) of the particles tries to restore the equilibrium structure. In a quiescent colloidal dispersion the particles move continuously in a random manner due to Brownian motion. The thermal motion establishes an equilibrium statistical distribution that depends on the volume fraction and interparticle potentials. Using the Einstein-Smoluchowski relation for the time scale of the motion, with the Stokes-Einstein equation for the diffusion coefficient, one can write the time taken for a particle to diffuse a distance equal to its radius R, as... 

The fact that the temporal occurrence of the motion events performed by the random walker is so broadly distributed that no characteristic waiting time exists has been exploited by a number of investigators [7,19,31] in order to generalize the various diffusion equations of Brownian dynamics to explain anomalous relaxation phenomena. The resulting diffusion equations are called fractional diffusion equations because in general they will involve fractional derivatives of the probability density with respect to the time. For example, in fractional noninertial diffusion in a potential, the diffusion Eq. (5) becomes [7,31]... 

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