Bromonaphthalene phosphor

De Silva et al. [28] prepared a naphthalene derivative (3) with logic functions (Scheme 1). Here, the bromonaphthalene unit exhibits phosphorescence in the presence of both the calcium ion and (3-CD [28], However, without them, oxygen quenches the phosphorescence of 2-bromonaphthalene phosphor because the protection effect of (3-CD is absent and photoinduced electron transfer from the tetracarboxylate receptor to the 2-bromonaphthalene phosphor occurs. Thus, phosphorescence output occurs only when the calcium ion and (3-CD inputs are active. The operation of these two inputs with a phosphorescence output corresponds to the AND logic function. The input to the NOT gate is oxygen. In the presence of oxygen without either calcium or (3-CD, the AND gate is disabled. 

Fig. 7. A three-input INHIBIT gate exemplified by the tetraanion 54 and /1-cyclodextrin (j8-CD). a With neither protons nor /1-CD present in the solution, phosphorescent output is low, because of both PET from the tertiary amine, and through intermolecular triplet-triplet collisions of the bromonaphthalene phosphor, b Addition of calcium ions leads to a reduction in the PET-based quenching of the phosphorescence - however, intermolecular collisions still lead to a low emission, c Shielding of the phosphor with /l-CD reduces intermolecular triplet annihilations, but quenching still occurs via PET. d Only with both Ca2+ and /1-CD present does the solution phosphoresce, e In any combination of Ca2+ and /1-CD, the solution will yield a low output in the presence of molecular oxygen (the INHIBIT stimulus), as a consequence of triplet-triplet collisions...

A newer gate 50 [116] replaces the Ca receptor within 49 with an aliphatic amine unit which binds H" ". The nitrogen atom in this amine unit serves as a PET donor to the triplet excited state of the bromonaphthalene phosphor. Therefore this is driven by H, p-cyclodextrin and O2 inputs where the last is the disabling input. 

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