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Bromofluorination of olefins

Bromoethyl)benzene, reaction with ethyl phenylacetate, 47, 72 ic-Bromofluorides from olefins, 46,12 Bromofluorination of olefins, 46, 39... [Pg.122]

Beside NXS, other effective electrophiles are -butylhypochlorite (combined with BF3)498, elementary chlorine (with SF4-HF)499 and KBr03 (with aqueous HF)500. A recent breakthrough in this area is the application of SiF4 (combined with Ar,Ar -dibromo-5,5 -dimethylhydantoin, DBDMH) for bromofluorination of olefins in a highly regio-, stereo-and chemoselective manner501,502. [Pg.562]

Bromofluorination of acyclic cis- and tran.v-olefins also proceeds with Markovnikov-type regiosclcctivity. anti Addition is observed for the trflM.s-olefins, while cA-olefins give both syn-and arm -addition products127. [Pg.1181]

See other pages where Bromofluorination of olefins is mentioned: [Pg.282]    [Pg.353]    [Pg.282]    [Pg.353]    [Pg.162]    [Pg.162]    [Pg.82]    [Pg.813]    [Pg.62]    [Pg.62]   
See also in sourсe #XX -- [ Pg.39 , Pg.46 ]

See also in sourсe #XX -- [ Pg.39 , Pg.46 ]

See also in sourсe #XX -- [ Pg.39 , Pg.46 ]



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Bromofluorination

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