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Bromination of phenanthrene

Phenanthrene-9-carbonitrile, prepared by bromination of phenanthrene to the 9-bromo derivative54 and its transformation by cuprous cyanide in dimethylform-amidess, served as starting material for the needed phenanthrene-9-acetonitrile (86). By the same sequence of steps as when converting phenanthrene- 1-carbonitrile (72a) to (81) the 9-carbonitrile was converted to (86), giving an overall yield of 60%. The standard procedure leads very smoothly to the triphenylenes (57) ... [Pg.165]


See other pages where Bromination of phenanthrene is mentioned: [Pg.130]    [Pg.11]    [Pg.26]   
See also in sourсe #XX -- [ Pg.19 , Pg.28 ]

See also in sourсe #XX -- [ Pg.19 , Pg.28 ]

See also in sourсe #XX -- [ Pg.19 , Pg.28 ]

See also in sourсe #XX -- [ Pg.19 , Pg.28 ]

See also in sourсe #XX -- [ Pg.129 ]




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