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Coordination bridge bidentate

Figure 2. Schematic representation of single-owf, single-in (monodentate) and bridging (bidentate) coordination of H2O to 18C6, and of the D3d bridging hydrate. Figure 2. Schematic representation of single-owf, single-in (monodentate) and bridging (bidentate) coordination of H2O to 18C6, and of the D3d bridging hydrate.
The IR spectrum of Co3(02CCi2Fl8C02)2.5(OHXH20)2 has Avas s of 135 cm 1, consistent with a bridging bidentate coordination mode.365 Similar data for Rh2(p-OOCH)4(dmf)2 and related complexes all show that the formato ligands are bridging.366... [Pg.324]

Reaction of MeBBr2 with pyrazoles in the presence of TIOEt and NEt3 yields the tris(pyrazolyl)borate thallium salts [Tl(MeTpx)j (Tpx = Tp, Tp or TpMe). In [Tl(MeTp )j a bridging bidentate coordination of MeTp is found, which has been explained as sterically enforced, on the basis of a comparison between the structure of [Tl(MeTp )] and [Tl(MeTpMe)].132... [Pg.42]

The value of AnC02 (about 120 cm ) for the acetato ligands in [Ru3(0)(0Ac)6(mpy)2-(CI0PY)]+, where mpy = 4-methyl pyridine, CIOPY = (NC5H4)CH2NHC(0)(CH2)ioSS(CH2)io-C(0)NH(C5H4N), confirms bridging bidentate coordination ... [Pg.310]


See other pages where Coordination bridge bidentate is mentioned: [Pg.101]    [Pg.107]    [Pg.114]    [Pg.352]    [Pg.215]    [Pg.537]    [Pg.423]    [Pg.436]    [Pg.437]    [Pg.438]    [Pg.215]    [Pg.385]    [Pg.329]    [Pg.153]    [Pg.157]    [Pg.168]    [Pg.170]    [Pg.178]    [Pg.186]    [Pg.217]    [Pg.191]   
See also in sourсe #XX -- [ Pg.2 , Pg.322 ]




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Bidentate bridges

Bidentate coordination

Bidentates

Bridging coordination

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