Branched chains with linear branching and chain breaking in the bulk

Branched chains with linear branching and chain breaking in the bulk 

Looking back at branched chain reactions with linear initiation and breaking in the bulk, we obtain equation [12.63], recalled here  

In section 12.6.3 we saw that when the branching factor cp is negative, the solution tends toward a pseudo-steady state. We now consider the case where the branching factor cp is positive cp 0. 

We notice that there is no limit to the concentration of the active center for infinities. The rate is therefore given by  

The concentration of the product formed (written as a partial pressure) becomes  

---