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Boronates, dinuclear structures

Few examples have been reported of metals coordinated to six-membered boron-sulfur heterocycles. Ashe et al. prepared 4-methyl-l,4-thiaborin (SC4H4BMe) which forms a stable molybdenum tricarbonyl sandwich complex 144.158 jn g etjert s laboratory, the reaction of the diborolyl complex 33 (Section 3.01.3.2) with COS afforded the dinuclear complex 145 whose structure was determined crystallographically.36 Other products, not involving boron-sulfur heterocycles and hence outside the scope of this discussion, were obtained via the treatment of 33 with different sulfur reagents such as CS2.36... [Pg.45]

Structure of a dinuclear heterometallic methoxide derivative containing lithium and boron, (MeOH)2Li(/x-OMe)2B(OMe)2 (Fig. 13), was detemiined by the X-ray diffraction method (124) both lithium and boron atoms were found to be four coordinate. [Pg.289]


See other pages where Boronates, dinuclear structures is mentioned: [Pg.1025]    [Pg.1025]    [Pg.536]    [Pg.139]    [Pg.324]    [Pg.325]    [Pg.1761]    [Pg.4113]    [Pg.385]    [Pg.60]    [Pg.138]    [Pg.264]    [Pg.1760]    [Pg.4112]    [Pg.31]    [Pg.112]    [Pg.263]   
See also in sourсe #XX -- [ Pg.17 , Pg.18 , Pg.19 , Pg.20 , Pg.21 , Pg.43 , Pg.44 , Pg.45 , Pg.46 ]

See also in sourсe #XX -- [ Pg.17 , Pg.18 , Pg.19 , Pg.20 , Pg.21 , Pg.43 , Pg.44 , Pg.45 , Pg.46 ]




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Boron structure

Boronates structure

Boronic structure

Dinuclear

Dinuclear structures

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