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Boron trifluoride model structure

A boron trifluoride molecule, BF3, has the Lewis structure shown in (5). There are three bonding pairs attached to the central atom and no lone pairs. According to the VSEPR model, as illustrated in Fig. 3.4, the three bonding pairs, and the fluorine atoms they link, lie at the corners of an equilateral triangle. Such a structure is trigonal planar, and all three F—B—F angles are 120° (6). [Pg.247]

The LE model is a simple but very successful model, and the rules we have used for Lewis structures apply to most molecules. To implement this model we have relied heavily on the octet rule. So far we have treated molecules for which this rule is easily applied. However, inevitably, cases arise where the importance of an octet of electrons is called into question. Boron, for example, tends to form compounds in which the boron atom has fewer than eight electrons around it—it does not have a complete octet. Boron trifluoride (BF3), a gas at normal temperatures and pressures, reacts very energetically with molecules such as water and ammonia that have available lone pairs. The violent reactivity of BF3 with electron-rich molecules occurs because the boron atom is electron-deficient. Boron trifluoride has 24 valence electrons. The Lewis structure that seems most consistent with the properties of BF3 is... [Pg.617]

Boron is a group IIIA element. Open the molecular model for boron trifluoride from the 3D Molecular Models section of the book s website. Near the boron atom, above and below the plane of the atoms in BF3, are two relatively large lobes. Considering the position of boron in the periodic table and the three-dimensional and electronic structure of BF3, what type of orbital does this lobe represent Is it a hybridized orbital or not ... [Pg.53]


See other pages where Boron trifluoride model structure is mentioned: [Pg.373]    [Pg.500]    [Pg.124]    [Pg.231]    [Pg.31]   
See also in sourсe #XX -- [ Pg.99 ]




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