Boron-containing polymers chemistry

The recent interest in boron tiitrogen-containing polymers has spurred some renewed interest in borazine preparations since these compounds are potential monomers. The direct reaction between (CIBNH)3 and NH3 produces an organic solvent insoluble polymer. In an attempt to control ammonolysis chemistry, the reactions of (Me2NBNH)3 with... 

Covering many areas of chemistry with boron at its centre, topics include applications to polyolefin catalysis, medicine, materials and polymers boron cluster chemistry, including carboranes and metal-containing clusters organic and inorganic chemistry of species containing only 1 or 2 boron atoms and theoretical studies of boron-containing compounds. New materials with novel optical and electronic properties are also discussed. 

The purpose of this chapter is to provide an overview of the chemistry, processing and application of boron-containing preceramic polymers in the BN system. The nonoxide precursor route, also called the Polymer Derived Ceramics (PDCs) route, represents a chemical approach based on the use of air- and/or moisture-sensitive (molecular or polymeric) precursors by means of standard Schlenk techniques and vacuum/argon lines. This precursor route allows the chemistry (e.g., elemental composition, compositional homogeneity and atomic architecture) of molecular precursors to be controlled and tailored in order to provide the ensuing preceramic polymers... 

Contemporary Boron Chemistry contains 80 reports in nine chapters. Clearly, since much research is interdisciplinary in nature, our decision to include a report in one particular section rather than another was sometimes an arbitrary one. With this caveat in mind, the sections are as follows Applications to Polyolefin Catalysis Materials and Polymers Medicinal Applications Cluster Synthesis Carboranes Metallaboranes Metallaheteroboranes Organic and Inorganic Chemistry of Mono- and Di-boron Systems and Theoretical and Computational Studies. 

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