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Boron bromide compound with

CHEMICAL PROPERTIES thermally unstable water reactive hydrolyzes in water to hydrogen and boric acid reacts with ammonia to form diborane diammoniate reacts slowly with bromine to form boron bromides reacts with hydrocarbons or organoboron compounds to give alkyl- or aryl-boron compounds reacts with metal alkyls to form metal borohydrides reacts with strong electron pair donors to form borane addition compounds FP (-90°C, -130°F) LFL/UFL (0.9%, 98%) AT (40-50°C, 104-122°F) HF (35.6 kJ/mol gas at 25°C). [Pg.539]

BBrj Boron bromide, 3 27, 29 BCls Boron chloride, 3 27, 28, 29 BCls CCHslsN Boron chloride-trimethylamine, 6 27 BCI3-PCI5 Boron chloride, compound with phosphorus (V) chloride, 7 79... [Pg.313]

It has been remarked earlier that the lone electron-pair in PC13 can be used for completion of an octet in boron compounds with BC13 it forms the compound C P.BCIs, the bromide and iodide have been prepared, a less stable compound is formed from BC13 and AsC13 and there is no reaction with SbCl3. [Pg.230]

Carbonyl bromide, or bromophosgene, was prepared for the first time by Emmerling by the oxidation of bromoform with potassium dichromate and sulphuric acid. Later it was also obtained by heating boron bromide to 150° C. with phosgene, but by this method a mixture with other compounds is obtained ... [Pg.74]

The boron trihalide complexes with a number of phosphine sulphides and selenides can be isolated for the chloride, bromide, or iodide but, consistent with its reduced Lewis acidity, the trifluoride does not react.600 Alkyldithio-phosphonic acids give tin, lead, and mercury derivatives such as Me3SnSP-(S)FEt, Pb[SP(S)FMe]2, and MeHgSP(S)FMe, which are monomeric in solution, and there is n.m.r. evidence for a bidentate phosphonate group in the tin compound.601 Vanadyl chelates of alkoxy-ethyl and alkoxy-phenyldi-thiophosphonates (87) have been synthesized and e.s.r. measurements... [Pg.383]


See other pages where Boron bromide compound with is mentioned: [Pg.8]    [Pg.565]    [Pg.139]    [Pg.12]    [Pg.201]    [Pg.113]    [Pg.59]    [Pg.92]    [Pg.113]    [Pg.163]    [Pg.945]    [Pg.1313]    [Pg.638]    [Pg.8]    [Pg.440]    [Pg.31]    [Pg.113]    [Pg.124]    [Pg.253]    [Pg.32]    [Pg.230]    [Pg.653]    [Pg.950]    [Pg.175]    [Pg.275]    [Pg.278]    [Pg.282]    [Pg.333]    [Pg.396]    [Pg.840]    [Pg.1069]    [Pg.1070]    [Pg.451]    [Pg.439]   
See also in sourсe #XX -- [ Pg.3 , Pg.3 , Pg.12 , Pg.141 , Pg.142 ]

See also in sourсe #XX -- [ Pg.3 , Pg.12 , Pg.41 , Pg.142 ]

See also in sourсe #XX -- [ Pg.3 , Pg.3 , Pg.12 , Pg.141 , Pg.142 ]




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