Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Bond lengths imide complexes

Related dinickel(II) p-N bridging compounds with NHC ligands were reported by Hillhouse et al. in 2009 (Scheme 10.31) [40]. [Ni(I)(p-Cl)(l Pr)]2 underwent one-electron oxidation by MesNj to afford a dinickel(II) bridging imide [ Ni(ll)(l Pr)(Cl) 2(p-NMes)] 66, in which one of the chlorides can be abstracted by NaBAr, to produce the dinickel(ll) ion pair compound 67. The Ni(ll)-Ni(ll) bond lengths in 66 and 67 are 2.5767(15) and 2.2911(8) A, respectively (Entries 5 and 6, Table 10.3). Complex 66 can also undergo one-electron reduction of the [(Ni(ll)Cl 2(p-NMes)] core, to afford a mixed-valent Ni(I)-Ni(II) compound 68, which upon treating with a one-electron oxidant gives 67 as the product. It is noteworthy that 67 and 68 bear similar core structures, but the Ni-Ni bond... [Pg.342]

See other pages where Bond lengths imide complexes is mentioned: [Pg.131]    [Pg.1266]    [Pg.19]    [Pg.266]    [Pg.88]    [Pg.61]    [Pg.52]    [Pg.180]    [Pg.183]    [Pg.420]    [Pg.428]    [Pg.303]    [Pg.235]    [Pg.335]    [Pg.66]    [Pg.258]    [Pg.245]    [Pg.233]    [Pg.91]    [Pg.258]   
See also in sourсe #XX -- [ Pg.74 ]

See also in sourсe #XX -- [ Pg.74 ]

See also in sourсe #XX -- [ Pg.74 ]

See also in sourсe #XX -- [ Pg.74 ]



SEARCH



Bond lengths complexes

Imide bonds

Imide complexes

© 2024 chempedia.info