Bond lengths ammine complexes

Alkene complexes Alkynyl complexes Ammine complexes Aqueous chemistry Arsine complexes Auranofin Auride ion Aurophilicity Binary compounds Bond lengths acetylacetonate complex alkyls and aryls ammine complexes carboxylates cyanide complexes dialkyl sulphide complexes dithiocarbamates to gold... 

Figure 3.100 Bond lengths in platinum(IV) ammine hydroxy complexes.

Alkene complexes Ammine complexes Aqueous chemistry Arsine complexes Binary compounds Bipyridyl complexes Bond lengths acetylacetonate alkene complexes alkyl and aryl complexes ammine complexes aqua ion... 

More accurate force constants for a number of transition metal complexes with ammine ligands have been derived by normal-coordinate analyses of infrared spectra[130, 31l The fundamental difference between spectroscopic and molecular mechanics force constants (see Section 3.4) leads to the expectation that some empirical adjustment of the force constants may be necessary even when these force constants have been derived by full normal-coordinate analyses of the infrared data. This is even more important for force constants associated with valence angle deformation (see below). It is unusual for bond-length deformation terms to be altered substantially from the spectroscopically derived values. 

Table A.2 has been derived from CSD, and, as a result, does not contain every precisely determined metal-ligand interatomic distance. For example, there are many ammine (M-NH3), carbonyl (M-CO), halide (M-Cl etc.) and aqua (M-OH2) complexes which do not fall within the scope of CSD. For such bond types and other metal-non-metal bond length information, the interested reader is referred to the Inorganic Crystal Structure Database [14].

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