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Copper-ligand bond energies

Figures 10.2 and 10.3 illustrate the electrochemistry for several copper(II) and copper complexes in MeCN. The redox potentials for these copper complexes and their ligands are summarized in Table 10.5 (related data for aqueous media are given in Table 10.6).3,8-13 In addition, the shift in redox potential (AE) for the free ligand (L) and when bonded in a complex (CuL ) is tabulated. This quantity is a measure of the apparent copper-ligand covalent-bond-formation free energy (—AGBF) ... Figures 10.2 and 10.3 illustrate the electrochemistry for several copper(II) and copper complexes in MeCN. The redox potentials for these copper complexes and their ligands are summarized in Table 10.5 (related data for aqueous media are given in Table 10.6).3,8-13 In addition, the shift in redox potential (AE) for the free ligand (L) and when bonded in a complex (CuL ) is tabulated. This quantity is a measure of the apparent copper-ligand covalent-bond-formation free energy (—AGBF) ...
Table 10.7 summarizes the copper-ligand bond energies for the various complexes. [Pg.410]

Deng, H. and Kebarle, P. (1998) Bond energies of copper ion-ligand L complexes CuL2+ determined in the gas phase by ion-ligand exchange equilibria measurements. J. Am. Chem. [Pg.396]


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See also in sourсe #XX -- [ Pg.41 , Pg.410 , Pg.495 ]




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