Blue-shifted hydrogen

The antibonding properties of the geminal a-a interactions has recently led to a theory of electron localization and its successful application to blue-shifting hydrogen bonds [129],... 

P. Hobza, Z. Havlas, Blue-shifting hydrogen bonds. Chem. Rev. 100, 4253 1264 (2000)... 

Spirko V, Hobza P (2006) Theoretical investigations into the blue-shifting hydrogen bond in benzene complexes. Chem Phys Chem 7 640-643... 

Kryachko ES, Karpfen A (2006) Theoretical force-field model for blue-shifted hydrogen bonds with fluoromethanes. Chem Phys 329 313-328... 

Scheiner S, Kar T (2002) Red versus blue-shifting hydrogen bonds Are there fundamental distinctions J Phys Chem A 106 1784-1789... 

B. Reimann, K. Buchhold, S. Vaupel, B. Brutschy, Z. Havlas, V. Spirko, and P. Hobza, Improper, Blue-shifting hydrogen bond between fluorobenzene and fluoroform, J. Phys. Chem. A 105, 5560-5566 (2001). 

K. Hermansson, Blue-shifting hydrogen bonds, J. Phys. Chem. A 106, 4695-4702 (2002). 

W. Zierkiewicz, D. Michalska, Z. Havlas, and P. Hobza, Study of the nature of improper blue-shifting hydrogen bonding and standard hydrogen bonding in the XsCH- -OH and XH- -0H2 complexes (X = F, Cl, Br, I) a correlated ah initio study, Chem. Phys. Chem. 3, 511-518 (2002). 

A. Karpfen, The interaction of fluorosilanes with hydrogen fluoride clusters strongly blue-shifted hydrogen bonds, J. Mol. Struct. (Theochem) 710, 85-95 (2004). 

A. J. Barnes, Blue-shifting hydrogen bonds—are they improper or proper J. Mol. Struct. 704, 3-9 (2004). 

Van der Veken, B.J., Herrebout, W.A., Szostak, R., Shchepkin, D.N., Havlas, Z., and Hobza, P., The nature of improper blue-shifting hydrogen bonding verified experimentally, J. Am. 

In some cases, the so-called blue-shifted hydrogen bond, the shift of the A-H stretching frequency is toward higher wave numbers. The reasons for this exceptional behavior have been now properly rationalized [39]. 

Jeffrey, G. A. (1997) An Introduction to Hydrogen Bonding, Oxford University Press, New York. Hobza, P. and Havlas, Z. (2000) Blue-shifting hydrogen bonds, Chem. Rev. 100, 4253 264. Hallam, H. E. (1973) Vibrational Spectroscopy of Trapped Species, John Wiley, New York. 

NEUTRAL BLUE-SHIFTING AND BLUE-SHIFTED HYDROGEN BONDS ... 

Charged blue-shifting hydrogen and -ir-hydrogen bonds are not considered in the present review. 

Neutral Blue-shifting and Blue-shifted Hydrogen Bonds... 

The current list of blue-shifting hydrogen bonds is quite impressive (see Table 3 which collects most of them, basically those which in some sense have become classical) and it considerably grows each year (interestingly, among more than 1000 articles published in Journal of Molecular Structure between 1982 and 1996, only nine were referred to the C-H- -B bonding, see Ref [50]). 

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