Block Copolymers Involving Single Hydrogen Bonding Groups

Block Copolymers Involving Single Hydrogen Bonding Groups 

HYDROGEN BOND FUNCTIONALIZED BLOCK COPOLYMERS AND TFI FCHELIC OLIGOMERS 

Nucleobase Containing Hydrogen Bonding Block Copolymers 

Spijker and colleagues (2005) synthesized nucleobase-functionalized block copolymers containing thymine via ATRP of a thymine methacrylate monomer from a poly(ethylene glycol) (PEG) macroinitiator. This polymer was introduced into the polymerization of an adenine containing an alkyl methacrylate 

---

Chain transfer reactions mostly proceed by abstraction of a monovalent atom such as hydrogen or a halogen. The scission of a bond carbon - oligovalent (e.g., H) atom is of interest for the introduction of endgroups into a polymer produced in a free radical reaction. Radically induced vinyl monomer polymerization with the possibility of chain transfer to a polymer of different chemical structure present in the reaction mixture leads to graft copolymers if bond scission occurs outside the main chain, no matter whether a single atom or a grouping is abstracted. Quite a different result is obtained if a radical attack involves a bond in the main chain of the polymer, if this bond scission occurs at a monovalent atom, which must be at the chain end, there is block copolymer formation. If bond scission occurs inside the polymer backbone, either block or random copolymers are produced [63]. 

---