Bismuthines synthesis

In 1996, we started more detailed investigations on group 13/15 compounds containing the heavier elements of group 15, Sb and Bi, focussing on the synthesis of aluminum and gallium stibines and bismuthines. At the same time. Wells et al. also began to prepare M—Sb adducts and heterocycles (M = B, Ga, In). These studies, which are the object of this review, resulted in... 

Scheme 3. Synthesis of group 13-stibine and bismuthine adducts.

Studies of the Lewis base complexes of ER3 compounds remains an active area of modern coordination chemistry, and we have described recent developments in the synthesis of arsine, stibine, and bismuthine ligands elsewhere in the present work (see Chapter 1.16). 

However, the current method for the synthesis of bismuthine, BiH3, is by the redistribution of methylbismuthine, BiHjMe. 

Synthesis of tris 2-[7V -bis(2-hydroxyethyl)sulfamoyl]phenyl bismuthine... 

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