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Bismuthines reactions with

Methyl bis(l-naphthyl)bismuthinate, Np.BiOCH,. The reagent is obtained in 80% yield by reaction of tris(l-naphthyl)bismuthine, Np3Bi, with chloramine-T in methanol. ... [Pg.214]

The reaction of tris(trifluoromethyl)bismuthine with chlorine, bromine, or iodine, however, has been found to yield the corresponding bismuth trihahde and trifluoromethyl hahde (61) ... [Pg.131]

Arsines are expected to show greater reactivity than phosphines, and H3AS, (CHsiHaAs, and (CHsiaHAs react spontaneously with perfluoroalkenes under mild conditions CgHsAsHa reacts similarly with CH2=CHCN . These reactions are summarized in Table 2 . No reactions of stibines and bismuthines with alkenes have been reported. [Pg.561]

Many trialkyl- and triaryl-bismuthines are known, although only a very small number have been used as ligands. References to specific BiR3 from earlier literature can be found in various reviews.9,10,12,15 The most widely used route is reaction of bismuth trihalide with the appropriate Grignard or organolithium reagent in diethyl ether or tetrahydrofuran. The air-stable... [Pg.382]

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Bismuthine

Bismuthine, methyldibromo triphenyl-, reaction with

Bismuthines

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