Bismuth III compounds with three Bi-S bonds

Bismuth(III) compounds with three Bi-S bonds (Tables 2.22 and 2.23) 

Bismuth compounds with three organyl oxygen ligands 

Mass spectral data are available for compounds 1 and 5-9 only an signal is reported for compound 1 [76ZAAC(423)47], while little fragmented ion peaks are observed in their El mass spectra for compounds 5-9. APCI mass spectral data of compounds 5,6,8 and 9 in MeCN with 1 % HCl exhibit a similar trend monocyclic bismuthenium cations provide predominant signals due to the cleavage of one Bi-S bond [96JA3225]. 

They can be prepared by the following three procedures (i) a substitution reaction between BiCl and thiolate anions [86POL1513, 93IC2972, 

CH2CI2, [(C6F5S)3Bi(dmpu)2l, (C6F5S)3Bi[S=C(NHMe)2]3l [(CaFsSIjBi (OSPh2)2l, and (C6F5S)3Bi[S=C(NH2)2] [95JCS(D)1163]. These 

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