Bis dimethylamido phosphoryl Chloride

Bis(dimethylamido)phosphoryl chloride has been prepared by the reaction of phosphorus (V) oxychloride with 

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Triphenyl)aminophosphonium chloride, synthesis 19 (Dimethylamido)phosphoryl dichloride, synthesis 20 Bis(dimethylamido)phosphoryl chloride, synthesis 21 Octamethylpyrophosphoramide, synthesis 22 Methylbromoarsines, sjmthesis 26... 

In a 1-1. three-necked round-bottomed flask equipped with a 50-ml. buret, a 500-ml. graduated dropping funnel, a thermometer, a stirrer, and an exhaust vent protected with a soda-lime drying tube, is placed 378.4 g. (2.22 mols) of bis(dimethylamido)phosphoryl chloride (synthesis 21). In the buret there is placed 20 ml. (1.11 mols) of water, in the graduated dropping funnel is added 232.0 g. (2.30 mols) of triethylamine, and the volume (approximately 320 ml.) is recorded. The contents of the reaction flask are heated to 45 to 50° and then the heater is removed. One milliliter of water is added, followed by one-twentieth (approximately 16 ml.) of the triethylamine. The reaction mixture is stirred until the mildly exothermic reaction subsides (ca. 5 minutes), and the addition of 1 ml. of water followed by... 

Barium iodate 1-hydrate, synthesis 4 Indium(I) bromide, synthesis 6 Hexachlorodisiloxane, synthesis 7 Trichlorosilanethiol, synthesis 8 Tris(acetylacetonato)silicon chloride, synthesis 9 Titanium(III)chloride, synthesis 11 Bis[tris(acetylacetonato)titanium(IV)] hexachloro-titanate(IV), synthesis 12 Zirconium(IV) iodide, synthesis 13 (Triphenyl) aminophosphonium chloride, synthesis 19 (Dimethylamido)phosphoryl dichloride, synthesis 20 Bis(dimethylamido)phosphoryl chloride, synthesis 21 Trimeric and tetrameric phosphonitrilic bromides, synthesis 23 Phosphorus(V) chloride-boron trichloride complex, synthesis 24... 

PON(CH3)2Cl2 (Dimethylamido)-phosphoryl dichloride, 7 69 PO(N(CH))2l2Cl Bis(dimethyl-amido)phosphoryl chloride,... 

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