Biopolymers starch esters

Extrusion is a cost effective manufacturing process. Extrusion is popularly used in large scale production of food, plastics and composite materials. Most widely used thermoplastics are processed by extrusion method. Many biopolymers and their composite materials with petroleum-based polymers can also be extruded. These include pectin/starch/poly(vinyl alcohol) (Fishman et al. 2004), poly(lactic acid)/sugar beet pulp (Liu et al. 2005c), and starch/poly(hydroxyl ester ether) (Otey et al. 1980), etc. In this study, composite films of pectin, soybean flour protein and an edible synthetic hydrocolloid, poly(ethylene oxide), were extruded using a twin-screw extruder, palletized and then processed into films by compression molding process or blown film extrusion. The films were analyzed for mechanical and structural properties, as well as antimicrobial activity. 

Emulsification of cellulose or starch with water or ethanol, soap and a fatty acid is a performing method to allow the grafting of fatty chains onto the biopolymer backbone. An experimental design allowed to determine the best conditions to synthesize starch fatty esters with DS < 0,5 using natural raw materials as reagents. 

The use of traditional composites made by glass, aramid, or carbon fiber-reinforced plastics has recently been discussed critically because of increasing environmental consciousness [8]. Thus, the recent research and development (R D) efforts have led to new products based on natural resources. Some of these are biodegradable polymers like PLA, cellulose esters, polyhydroxyalkan-otes (PHAs), and starch polymers. Furthermore, natural fiber-reinforced plastics made of natural fibers like flax, hemp, kenaf, jute, and cotton fibers are important R D achievements. Composites made of natural fibers and biopolymers... 

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