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Bioorthogonal chemical reporter

Chang PV, Prescher JA, Hangauer MJ, Bertozzi CR (2007) Imaging cell surface glycans with bioorthogonal chemical reporters. J Am Chem Soc 129 8400-8401... [Pg.64]

Figure 1. The bioorthogonal chemical reporter strategy. First, unnatural monosaccharides are metabolically incorporated into glycoconjugates. Next, the unnatural functionality (black square) is covalently tagged using appropriately derivatized reagents (white square). Figure 1. The bioorthogonal chemical reporter strategy. First, unnatural monosaccharides are metabolically incorporated into glycoconjugates. Next, the unnatural functionality (black square) is covalently tagged using appropriately derivatized reagents (white square).
Hang HC, Wilson JP, Charron G (2011) Bioorthogonal chemical reporters for analyzing protein lipidation and Upid trafficking. Acc Chem Res 44 699-708... [Pg.58]

Neef AB, Pernot L, Schreier VN, Scapozza L, Luedtke NW (2015) A bioorthogonal chemical reporter of viral infection. Angew Chem Int Ed 127 8022-8025... [Pg.59]

Covalent Tagging of Chemical Reporters Using Bioorthogonal... [Pg.260]

Diels-Alder (DA) reaction is one of the most useful chemical transformations. This reaction typically proceeds slowly in the absence of a catalyst, but can be accelerated with the use of Lewis acids [75], It is characterized by high yield under various conditions, has less sensitivity against solvents, and does not produce byproducts. It is characterized by high yield under various conditions, insensitive toward solvent polarity, and little byproducts. Indeed, the tetrazine/trani-cy-clooctene based inverse electron-demand DA reaction has become the most popular bioorthogonal reaction in the literature because of its fast reaction kinetics [76]— second-order rate constant as high as 2.8 x 10 s has been reported [77], So... [Pg.98]

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