Biocatalytic methodologies polymerization

Relatively very few reports exist on use of biocatalytic methodologies for carrying our surface modification of SAMs. Use of enzymes in organic synthesis (77) and polymer science (78) is well established and has been discussed elsewhere in comprehensive reviews. The rapidly increasing interest in in vitro enzyme-catalyzed organic and polymeric reactions has been due to the fact that several families of enzyme utilize and transform not only their natural substrates but also a wide range of unnatural compounds to yield a variety of useful... 

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