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BINAPHOS-type ligands

Second generation BINAPHOS-type ligands have been developed recently. Placing 3-methoxy substituents on the aryl phosphine unit furnishes a catalyst which allows for an enantioselective hydroformylation of vinylfurans (Scheme 19) [68]. [Pg.159]

Tab. 2 Enantioselective hydroformylation of styrene using rhodium catalysts of BINAPHOS-type ligands immobilized in scC02. Tab. 2 Enantioselective hydroformylation of styrene using rhodium catalysts of BINAPHOS-type ligands immobilized in scC02.
FIGURE 14.4. Modified Binaphos-type ligands, and the general structure of carbohydrate-derived phosphites. [Pg.405]

In addition to a-olefins, p-/-butylstyrene can be used as a comonomer for the isotactic specific copolymerization with carbon monoxide with chiral induction [32], Whereas bipyridyl as ligand gives a syndiotactic polymer, the Pd-catalyzed polymerization with ligand 11 leads to a polymer with isotacticity of over 98% and high optical activity ([ ]D -536° (in CH2C12)) [33, 34]. The BINAPHOS catalyst described above is also effective in this type of copolymerization [25],... [Pg.762]

See other pages where BINAPHOS-type ligands is mentioned: [Pg.919]    [Pg.479]    [Pg.919]    [Pg.479]    [Pg.68]    [Pg.455]    [Pg.192]    [Pg.157]    [Pg.447]    [Pg.390]    [Pg.761]    [Pg.15]    [Pg.707]    [Pg.36]    [Pg.132]    [Pg.704]    [Pg.56]    [Pg.761]   
See also in sourсe #XX -- [ Pg.151 ]

See also in sourсe #XX -- [ Pg.151 ]



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BINAPHOS

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