Bifurcation subcritical antipitchfork

Figure 10. Same as Fig. 9 for the subcritical antipitchfork bifurcation scenario for symmetric XYX. 

As the energy increases in the interval E < E < Ea, the orbits Y and 2 progressively shift toward the symmetric-stretch orbit 0 and merge at the subcritical antipitchfork bifurcation. Just below this bifurcation, 1 and 2 are elliptic while 0 is still hyperbolic (without reflection). Between and Ea, the periodic orbits 1 and 2 may either remain of elliptic type or become hyperbolic in the energy interval [ , "1 such that E < Edd> < Edd < Ea. 

This dissociative system, which represents the prototype system for chemical reaction dynamics, has been the object of many studies. Child et al. [143] have carried out a detailed analysis of the classical dynamics in a collinear model based on the Karplus-Porter surface. These authors have introduced the concept of PODS and first observed the subcritical antipitchfork bifurcation scenario in this system. 

The bottom of the exit channels is at -3194 cm-1 if the origin corresponds to the saddle of the Karplus-Porter surface. The pair of tangent bifurcations occur at E = 1670 cm 1, which is followed by the subcritical antipitchfork bifurcation at Ea = 2633 cm 1. The bifurcation scenario is thus similar to the CO2 system, and we may expect a three-branch Smale horseshoe in this system as well. 

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