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Bicyclo octane, reaction with salts

The silyl-bridged four-membered rings are not A, B observed in these reactions with aminofluorosilyl-substituted rings. These Li salts react by one route to triply substituted products they also form bicyclo[4.2.0]octanes by an intramolecular reaction with LiF elimination and silyl group and methanide ion migration . Figure 4 shows the structure of compound... [Pg.214]

Carbene formation during vacuum-UV photolysis (7.6 eV) and radiolysis of cyclooctane by unimolecular H2 elimination from a single carbon atom (1,1-elimination) was shown to be the main reaction channel of excited cyclooctane (equation 6)". The carbene 6 is formed with an efficiency close to 100% in the long-wavelength photolysis of the sodium salt of the p-tosylhydrazone 7 as well as in the vacuum-UV photolysis and radiolysis of cyclooctane. This was deduced from the similar product distribution of both reactions to give cyclooctene (8), bicydo[3.3.0]octane (9) and bicyclo[5.1.0]octane (10) ... [Pg.690]

See other pages where Bicyclo octane, reaction with salts is mentioned: [Pg.129]    [Pg.379]    [Pg.561]    [Pg.272]    [Pg.266]    [Pg.335]    [Pg.489]    [Pg.90]    [Pg.1125]    [Pg.1292]    [Pg.471]    [Pg.90]    [Pg.395]    [Pg.123]    [Pg.1292]    [Pg.363]   
See also in sourсe #XX -- [ Pg.642 ]



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Bicyclo octan

Bicyclo octane

Octanes, reaction

Reactions with salts

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