Bicyclo octane naphthalene

Okayama, Japan. The synthetic procedures for S-D dyads and their reference compounds shown in Fig. 6 are illustrated in Fig. 7, where a naphthalene and a ferrocene moiety are used as an S and a D moiety, respectively. For comparison of photoinduced electron transfer rates between a single alkyl chain and a triple alkyl chain as the spacers of the S-D dyads with the same length of four-carbons, S-D dyads with a rigid spacer with a bicyclo[2.2.2]octane were synthesized [39]. The synthetic procedure for the S-D dyads with the rigid spacer is also shown in Fig. 8 [39], Other amphiphilic compounds and chemicals were commercially available. 

C-C bond formations. Iron(III) perchlorate effects cyclization of 1,5-cyclooctadienes to bicyclo[3.3.0]octane derivatives and oxidative dimerization of naphthalenes. Thiols are also oxidized to give disulfides. 

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