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Bicyclo hepta-2,5-diene, ruthenium complex

The strongly chelating dienes bicyclo[2,2,l]hepta-2,5-diene (1) and cyclo-octa-1,5-diene (12) react with ruthenium halides to give stable, diamagnetic complexes of the composition [RuX2(diene)] (X = Cl, Br, I). Note added in proof. [Pg.92]

The ( /4-bicyclo[2.2.1]hepta-2,5-diene)bis( /3-2-propenyl)ruthenium(II) and (>/4-cycloocta-l,5-diene)bis(>/3-2-propenyl)ruthenium(II) complexes have previously been reported,5,6 but we present here scaled-up procedures that produce synthetically useful quantities of these compounds. The preparation of Grignard reagents is based upon the methods described by Eisch.7... [Pg.250]

See other pages where Bicyclo hepta-2,5-diene, ruthenium complex is mentioned: [Pg.352]    [Pg.378]    [Pg.352]    [Pg.394]    [Pg.250]    [Pg.250]   
See also in sourсe #XX -- [ Pg.26 , Pg.250 ]

See also in sourсe #XX -- [ Pg.26 , Pg.250 ]

See also in sourсe #XX -- [ Pg.26 , Pg.250 ]

See also in sourсe #XX -- [ Pg.26 , Pg.250 ]



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1.3- Dienes complexes

Bicyclo hepta-2,4-dienes

Bicyclo hepta-2,5-diene (

Bicyclo hepta-2,5-diene, ruthenium

Complex diene

Diene ruthenium complexes

Hepta

Hepta-1,6-dienes

Hepta-2,5-diene

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