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Bicyclo hepta-2,5-diene, ruthenium

The strongly chelating dienes bicyclo[2,2,l]hepta-2,5-diene (1) and cyclo-octa-1,5-diene (12) react with ruthenium halides to give stable, diamagnetic complexes of the composition [RuX2(diene)] (X = Cl, Br, I). Note added in proof. [Pg.92]

The ( /4-bicyclo[2.2.1]hepta-2,5-diene)bis( /3-2-propenyl)ruthenium(II) and (>/4-cycloocta-l,5-diene)bis(>/3-2-propenyl)ruthenium(II) complexes have previously been reported,5,6 but we present here scaled-up procedures that produce synthetically useful quantities of these compounds. The preparation of Grignard reagents is based upon the methods described by Eisch.7... [Pg.250]

G. p-AQUA-BIS( i-TRICHLOROACETATO)-BIS[(q4-BICYCLO[2.2.1]-HEPTA-2,5-DIENE) (TRICHLOROACETATO)RUTHENIUM(II)]... [Pg.256]

C12RuC7Hk, Ruthenium(II), (V-bicyclo-[2.2.1]hepta-2,5-diene)dichloro-, 26 250 C12RuC H 2, Ruthenium(II), dichloro(V-cy-cloocta-1,5-diene)-, 26 253... [Pg.417]

The ruthenium-catalysed homo Diels-Alder [2+2+2] cycloaddition reaction between alkynyl phosphonates (601) and bicyclo[2.2.1]hepta-2,5-diene (600) providing the corresponding phosphonate substituted delta-cyclenes (602) in low to good yields (up to 88%) as studied by Kettles, Cockburn and Tam (Scheme 148). ... [Pg.155]

See other pages where Bicyclo hepta-2,5-diene, ruthenium is mentioned: [Pg.352]    [Pg.378]    [Pg.352]    [Pg.394]    [Pg.250]    [Pg.251]    [Pg.173]    [Pg.356]    [Pg.415]    [Pg.468]    [Pg.124]    [Pg.250]    [Pg.251]   


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Bicyclo hepta-2,5-diene (

Bicyclo hepta-2,5-diene, ruthenium complex

Hepta

Hepta-1,6-dienes

Hepta-2,5-diene

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