Between Porphyrin Photoreactivity in Bulk Solutions and at the ITIES

Comparison Between Porphyrin Photoreactivity in Bulk Solutions and at the ITIES 

Another interesting comparison can be made with the charge transfer dynamics observed in porphyrin-ferrocene dyads. These supramolecular structures feature porphyrin and ferrocene units covalently linked. Imahori et al. have shown that the quenching of zinc tetraphenylporphyrin-ferrocene dyads takes place via the singlet state with a rate constant in the range of 10 s . This rate con- 

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