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Benzothiete sulfones

Benzothiete sulfone, when treated with LiAlH4 and H30, did not lead to the product corresponding to 232 but rather to o-toluenethiol. ... [Pg.260]

The mass spectra of several thiete sulfones have been interpreted on the basis of ring-opening to the cyclic sulfinate (sultine). Benzothiete sulfones lose sulfur dioxide to give benzocyclopropenium ions. The peri effect in 1,8-disubsti-tuted naphthalene derivatives, for example, 205b, has been discussed. ... [Pg.531]

Electrolysis of benzothiete sulfone 269 yields the phenylmethanesulfinate anion (major) and the o-toluenesulfinate anion (minor).Thermolysis 618,619 gj. photolysis of thiete 1,1-dioxides proceeds via ring-opening to vinyl sulfines, for example. 288, which have been trapped by reaction with water, phenol,methanol, or norbornenes. These intermediates may recyclize to unsaturated sultines (cyclic sulfinate esters) (e.g., 289) or lose sulfur monoxide to give mainly the trans isomers of a,j3-unsaturated carbonyl compounds (e.g., 290). Mass spectra also indicate the formation of unsaturated sultines. ... [Pg.545]

The first thiete fused to an aromatic system 219 (and an anthracene derivative) was reported in 1965 and was prepared by reduction of a naphthothiete sulfone. An attempt to prepare benzothiete by desulfurization of benzo-l,2-dithiolane was unsuccessful. Photolysis of benzo-l,2-dithiolane 1,1-dioxide in an attempt to extrude sulfur dioxide to give benzothiete also was unsuccessful. The naphthothiete 205, however, was prepared by extrusion of sulfur dioxide from 220 and nitrogen from 221. Thiete 205 also is obtained in 6-8% yield by treatment of 1,8-dehydronaphthalene with carbon disulfide. The unstable thiolactone 211 was formed by a photochemical extrusion of benzaldehyde from 222 and from 222a at 350°C. The benzothietes 209, 223, " and 224 have been... [Pg.516]


See other pages where Benzothiete sulfones is mentioned: [Pg.539]    [Pg.541]    [Pg.539]    [Pg.541]    [Pg.679]    [Pg.679]    [Pg.91]    [Pg.890]    [Pg.529]   
See also in sourсe #XX -- [ Pg.531 ]




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Benzothiete

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