Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Haloform reaction benzoic acid

The Haloform reaction is catalyzed by cyclodextrins in what the authors label as inverse phase transfer catalysis, 25 but the synthetic utility of this variation remains to be seen. An alternative to the use of halogen is a nitroarene catalyzed oxidation of acetophenone with sodium percarbonate or sodium perborate.26 However, the yields of substituted benzoic acids furnished by this method are mediocre (23-73%) in comparison to the conventional Haloform conditions. Likewise, the Haloform reaction of acetone with iodine in liquid ammonia is without synthetic merit (8-12%).27... [Pg.612]

Hypochlorite Oxidation of Methyl Ketones by the Haloform Reaction Benzoic Acid and p-Methoxybenzoic Acid... [Pg.403]

NMR spectra. See also nuclear magnetic resonance spectroscopy chemical shifts, 573-574 interpretation, 571-573 spin-spin coupling, 574-576 IMS, 582 halide ion, 637 haloform reaction, 403-408 benzoic acid synthesis, 405-406 p-methoxybenzoic acid, 406-407 semimicroscale preparation, 407 08 halogenation... [Pg.674]

An example of the haloform reaction is the oxidation of propio-phenone to benzoic acid in 96% yield [5]. [Pg.64]


See other pages where Haloform reaction benzoic acid is mentioned: [Pg.295]    [Pg.331]    [Pg.16]   
See also in sourсe #XX -- [ Pg.619 ]




SEARCH



Benzoic acid reactions

Benzoic reaction

Haloformates

Haloforms

© 2024 chempedia.info