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3- Methoxybenzoic acid

Ethyl indole-2-carboxylate 4-Methoxybenzoic acid, TFAA, H3PO4 74 [11]... [Pg.114]

Ewins has synthesised both substances from m-methoxybenzoic acid, which on nitration gave 2-nitro-3-methoxybenzoic acid, and this, on reduction and treatment with methyl iodide, yielded damasceninic acid, which, by esterification with methyl alcohol, furnished damascenine. Kaufmann and Rothlen found that the additive product of 8-methoxy-quinoline and methyl sulphate, on oxidation with permanganate, yields formyldamasceninic acid, MeO. CgH3(NMe. CHO). COOH, which can be transformed into damasceninic acid by warming with dilute hydrochloric acid. ... [Pg.633]

Results of the sulfur tetrafluoride fluorination of benzenecarboxylic acids strongly depend on the nature of a benzene ring substituent Benzoic, toluic, and particularly p-methoxybenzoic acids give poor yields of the respective benzotri-... [Pg.244]

Nitration of quinindoline gave the expected 9-nitro derivative (261). A single mononitro compound was formed from the 3,4-dihydro-jS-carboline, harmaline this was 6-nitroharmaline, since on oxidation it yielded 3-nitro-4-methoxybenzoic acid. [Pg.144]

Suitable substrates for the Hunsdiecker reaction are first of all aliphatic carboxylates. Aromatic carboxylates do not react uniformly. Silver benzoates with electron-withdrawing substituents react to the corresponding bromobenzenes, while electron-donating substituents can give rise to formation of products where an aromatic hydrogen is replaced by bromine. For example the silver /)-methoxybenzoate 6 is converted to 3-bromo-4-methoxybenzoic acid 7 in good yield ... [Pg.168]

It has been prepared synthetically by Ewins in the following manner Meta-oxybenzoic acid is converted with the aid of dimethyl sulphate into m-methoxybenzoic acid, which is then nitrated, and from the nitration products 2-nitro-3-methoxybenzoic acid is separated. This is reduced to 2-amino-3-methoxybenzoic acid which on heating with methyl iodide, yields 2-methylamino-3-methoxybenzoic acid. On warming this with freshly precipitated silver chloride it yields damascenine hydrochloride. [Pg.291]

An example of a reaction series in which large deviations are shown by — R para-substituents is provided by the rate constants for the solvolysis of substituted t-cumyl chlorides, ArCMe2Cl54. This reaction follows an SN1 mechanism, with intermediate formation of the cation ArCMe2 +. A —R para-substituent such as OMe may stabilize the activated complex, which resembles the carbocation-chloride ion pair, through delocalization involving structure 21. Such delocalization will clearly be more pronounced than in the species involved in the ionization of p-methoxybenzoic acid, which has a reaction center of feeble + R type (22). The effective a value for p-OMe in the solvolysis of t-cumyl chloride is thus — 0.78, compared with the value of — 0.27 based on the ionization of benzoic acids. [Pg.496]

Quinoxalinediamine (172) and p-methoxybenzoic acid gave 2-p-methoxy-phenyl-17/-imidazo[4,5-/]quinoxaline (174) [neat synthon (2 equiv), 210°C,... [Pg.291]

CH3NO2 75-52-5) see Baclofen Gabapentin Midazolam Pirbuterol Ranitidine Ropinirole Trometaniol l-(2-nitro-4-methoxyphenyl)-2-nitropropcnc C oHi()N203 25803-11-6) see Clometacin 4-(5-nitro-l-methylindol-3-ylmethyl)-3-methoxybenzoic acid... [Pg.2426]

In order to extend the scope of the reaction, and with the aim of designing a greener approach to the above set of reactions, we preformed the acylation of the same substrates with different acylation agents, such as maleic anhydride, p-methoxybenzoic acid and acetic acid (Scheme 48.4). Table 48.3 shows the results for acylation of benzenesulfonamide. [Pg.431]

Maleic anhydride p-methoxybenzoic acid Acetic acid ... [Pg.432]


See other pages where 3- Methoxybenzoic acid is mentioned: [Pg.673]    [Pg.779]    [Pg.827]    [Pg.563]    [Pg.563]    [Pg.563]    [Pg.600]    [Pg.600]    [Pg.600]    [Pg.879]    [Pg.883]    [Pg.883]    [Pg.883]    [Pg.285]    [Pg.285]    [Pg.633]    [Pg.827]    [Pg.67]    [Pg.760]    [Pg.1306]    [Pg.387]    [Pg.387]    [Pg.498]    [Pg.24]    [Pg.123]    [Pg.364]    [Pg.1944]    [Pg.1947]    [Pg.2298]    [Pg.2341]    [Pg.2347]    [Pg.1191]    [Pg.427]    [Pg.467]    [Pg.202]    [Pg.63]    [Pg.22]   
See also in sourсe #XX -- [ Pg.2 , Pg.207 ]




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2- methoxybenzoate

Methoxybenzoates

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