Benzene, methyl-, cobalt complex manganese complexes

C7H4N, Benzonitrile platinum complex, 26 345 ruthenium (II) complexes, 26 70-72 CiH , Benzene, methyl-cobalt complex, 26 309 manganese complex, 26 172... 

C,oH, Benzene, l-isoprq>yl-4-methyl-, tulhenium complex, 21 75 C oH t, 1,3-Cyclopentadiene, 1,2,3,4,5 penta-methyl, 21 181 cobalt complexes, 23 15-19 iridium and riiodium complex, 22 173, 174 CijHit, Benzene, hexamethyl-, nithenium complexes, 21 74-77 CajMnjOi, Calcium manganese oxide, 22 73 CdCl2N O9C2 H]0. Cadmium(II), aqua-... 

Epoxidation of olefins was catalyzed by the ruthenium(II) complex of the above perfluorinated y3-diketone in the presence of 2-methylpropanal (Scheme 50). Unfunctionalized olefins were epoxidized with a cobalt-containing porphyrin complex, and epoxidation of styrene derivatives was catalyzed by chiral salen manganese complexes (248) (Scheme 50). In the latter case, chemical yields were generally high, however, the products showed low enantiomeric excess with the exception of indene (92% ee). [Pd(C7Fi5COCHCOC7Fi5)2] efficiently catalyzed the oxidation of terminal olefins to methyl ketones with f-butylhydroperoxide as oxidant in a benzene-bromoperfluoro-octane solvent system (Scheme 50). In all these reactions, the product isolation and efficient catalyst recycle was achieved by a simple phase separation. 

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