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Basic zinc acetate’ building unit

Figure 9.42 Secondary Building Units (SBU) using carboxylates with rigid coordination geometries that replace metal ions as vertices in MOFs. (a) Paddlewheel or lantern structure as in 9.17, (b) octahedral basic zinc acetate SBU used in MOF-5 and (c) a trigonal prismatic oxo-centred trimer. The poly-hedra use carboxylate carbon atoms as their vertices and the MOFs propagate via the linkers attached to these carbon atoms. The metal atoms are bound to only terminal ligands in addition to those shown. Figure 9.42 Secondary Building Units (SBU) using carboxylates with rigid coordination geometries that replace metal ions as vertices in MOFs. (a) Paddlewheel or lantern structure as in 9.17, (b) octahedral basic zinc acetate SBU used in MOF-5 and (c) a trigonal prismatic oxo-centred trimer. The poly-hedra use carboxylate carbon atoms as their vertices and the MOFs propagate via the linkers attached to these carbon atoms. The metal atoms are bound to only terminal ligands in addition to those shown.
Figure 9 Metal-carboxylate clusters commonly encountered and utilized as MBBs. Left is the actual cluster and the right is the conceptual secondary building unit (SBU) depiction, (a) Binuclear tetracarboxylate paddle wheel M2(RC02)4, (b) basic chromium acetate trimer M30(RC02)6(H20)3, and (c) basic zinc acetate, M40(RC02)6, R represents the organic linker, the points of extensions are highlighted in yellow. Metal ion (green), C (gray), N (blue), and O (red). ... Figure 9 Metal-carboxylate clusters commonly encountered and utilized as MBBs. Left is the actual cluster and the right is the conceptual secondary building unit (SBU) depiction, (a) Binuclear tetracarboxylate paddle wheel M2(RC02)4, (b) basic chromium acetate trimer M30(RC02)6(H20)3, and (c) basic zinc acetate, M40(RC02)6, R represents the organic linker, the points of extensions are highlighted in yellow. Metal ion (green), C (gray), N (blue), and O (red). ...
See other pages where Basic zinc acetate’ building unit is mentioned: [Pg.5706]    [Pg.5705]    [Pg.276]    [Pg.781]    [Pg.323]    [Pg.114]    [Pg.164]    [Pg.242]    [Pg.169]   
See also in sourсe #XX -- [ Pg.579 , Pg.584 ]



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