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Band structure terms Links

The A, B and C terms are related to flow anisotropy, molecular longitudinal diffusion and mass transfer processes, respectively. The theoretical support for the Knox equation was derived by Horvath [12]. The A term cannot be expressed simply. The theoretical treatment links A to structural parameters of the column packing, porosity, pore volume, pore diameter and tortuosity [12]. A is related to the flow pattern and the general band spreading due to "eddy" diffusion [13]. The B term (longitudinal molecular diffusion) was written as [13] ... [Pg.176]


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