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Baeyer-Villiger oxidation fragment synthesis

The Baeyer-Villiger oxidation is used in diastereoselective synthesis of GH fragment of ciguatoxin starting from 2-bromo-2-cyclohexenone <1997SL307>. [Pg.69]

A Baeyer-Villiger oxidation has the potential of being asymmetric if a regioselective reaction is conducted on a meso-substrate or if a stereodifferentiated stereogenic center is already present. The oxidation can be chemical or enzymatic.213-215 216 An example of a chemical reagent in a Baeyer-Villiger reaction is provided in the synthesis of fragment A 26 from /f-carvone (27) (Scheme 9.38) as part of a synthesis of Cryptophycin A (28).217... [Pg.140]

See other pages where Baeyer-Villiger oxidation fragment synthesis is mentioned: [Pg.319]    [Pg.319]    [Pg.388]    [Pg.141]    [Pg.368]    [Pg.345]    [Pg.527]    [Pg.531]    [Pg.604]   
See also in sourсe #XX -- [ Pg.293 , Pg.298 ]



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Baeyer-Villiger synthesis

Oxidative fragmentations

Oxidizer fragments

Synthesis fragmentation

Villiger

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