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Azetidinone with enol ethers

Of the new methods of preparation of oxo derivatives of the 5,6-dihydro-4//-1,3-oxazines, the most important is that developed by Martin and co-workers 169 the reaction of acylisocyanates with enol ethers at room temperature under nitrogen yields 48 [Eq. (35)] (see also Arbuzov et a/.170-171) together with an isomeric azetidinone. The... [Pg.22]

Reactions of Azetidinone Sulfenic Acids with Halogenating Reagents. Conjugate Addition Reactions of Azetidinone Sulfenic Acids. Reaction of Azetidinone Sulfenic Acids with Enol Ethers. [Pg.1]

V. Reaction of Azetidinone Sulfenic Acids with Enol Ethers... [Pg.29]

As discussed in Section 2.3.3.1, enol stannyl ethers react with carbonyl compounds readily without the need for catalysts. However, catalytic amounts of AgBp4 and h have bron found to improve considerably the yield of the condensation of the tin(II) enol ether (159) with the azetidinone (93). The use of a catalytic amount of PdCl2[P(o-MeC6H4)3]2 improves the yield of the reactions between enol stannyl(IV) ethers and aldehydes. ... [Pg.624]

In the Kaneka approach [12], silyl enol ether 14 is obtained from the starting butyrate by sequential 0-protection, reduction to the aldehyde and treatment with TMS-Cl/TEA. Cycloaddition with CSI and reductive N-de-chlorosulfonylation with either LAH or PhSH affords azetidinone 17. Much emphasis is placed on the conversion 17 11, since 4-hydroxyazetidinones... [Pg.617]


See other pages where Azetidinone with enol ethers is mentioned: [Pg.77]    [Pg.426]    [Pg.649]    [Pg.649]    [Pg.621]    [Pg.152]    [Pg.92]    [Pg.8]    [Pg.649]    [Pg.84]    [Pg.359]    [Pg.154]   
See also in sourсe #XX -- [ Pg.29 ]




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Enol ether reaction with azetidinone

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