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Asymmetric Synthesis of Unsymmetrical Allylic Alcohols

It was then of interest to see whether racemic unsymmetrical allylic carbonates are also capable of undergoing an efficient catalytic transformation to the corresponding allylic alcools with Pd(0)/BPA and water. [Pg.244]

BPA catalyst. This seems to point to a Pd(0)/BPA-catalyzed isomerization of the 7t-allyl-Pd(ll) complexes being responsible for the dynamic part of the kinetic resolution. [Pg.245]

Scheme 2.1.4.30 Asymmetric synthesis of unsymmetrical allylic alcohols.

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Alcohols synthesis

Allyl alcohols, asymmetric synthesis

Allyl alcohols, synthesis

Allyl synthesis

Allylation: of alcohols

Allylic alcohols asymmetric

Allylic synthesis

Asymmetric allylation

Asymmetric synthesis of alcohols

Synthesis of Allylic Alcohols

Synthesis of alcohols

Synthesis unsymmetrical

Unsymmetric