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Aryl groups, neighbouring group participation

Cyclization. A kinetic study on the rates of jff-chloroethylamine cyclization to aziridines revealed the role of neighbouring aryl group participation, and led to the postulation of a reaction scheme which explains the salt effects, the activation parameters, and the changes in rates. The Gabriel synthesis has been applied to a-chloroamides in the presence of potassium t-butoxide to yield 3-(l-adamantyl)aziridinones (211) accompanied by a low yield of the... [Pg.39]

See other pages where Aryl groups, neighbouring group participation is mentioned: [Pg.320]    [Pg.126]    [Pg.126]    [Pg.13]    [Pg.120]    [Pg.51]    [Pg.195]    [Pg.409]    [Pg.261]    [Pg.292]    [Pg.736]    [Pg.131]   
See also in sourсe #XX -- [ Pg.973 ]

See also in sourсe #XX -- [ Pg.973 ]

See also in sourсe #XX -- [ Pg.973 ]



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Aryl groups

Aryl groups, neighbouring group

Neighbouring group participation

Neighbouring-group

Participating group

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