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Oxygen—arsenic bonds reactions with

Bonds to Oxygen.—Mossbauer data have been obtained for (Ph2Sb)20 and a series of trialkoxystibines Sb(OR)3, where R = Et, Pr, Bun, or Bu. 756 Cyclic esters, analogous to those discussed above for arsenic, can be obtained with antimony as the central atom by reactions between PhSbCl2 and diols, dithiols, or monothioglycols.757... [Pg.399]

The SRN1 process has proven to be a versatile mechanism for replacing a suitable leaving group by a nucleophile at the ipso position. This reaction affords substitution in nonactivated aromatic (ArX) compounds, with an extensive variety of nucleophiles ( u ) derived from carbon, nitrogen, and oxygen to form new C—C bonds, and from tin, phosphorus, arsenic, antimony, sulfur, selenium, and tellurium to afford new C-heteroatom bonds. [Pg.319]

Phosphorus forms stronger bonds with oxygen than do nitrogen or arsenic. The formation of the very strong phosphoryl bond is the driving force for many reactions. Rearrangement reactions of phosphorus frequently involve the formation of this linkage ((3.69) and (3.70)). [Pg.71]


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Arsenic reactions

Arsenic reactions with

Arsenic—oxygen bonds

Reaction with oxygen

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