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Argentic picolinate

The use of silver (II) salts, particularly argentic picolinate, as reagents for hydroxyl oxidation has also been disclosed recently. The reaction may be run in acid, neutral or basic media in aqueous or polar organic solvents at room or slightly elevated temperatures. Primary alcohols may be oxidized to aldehydes or acids depending on the conditions used. Amines and trivalent phosphorous compounds are more sensitive to oxidation with this reagent than are hydroxyl groups. [Pg.241]

Androst-4-ene-3,ll,17-trione, 88, 377, 409 di-Androst-5-en-3/3-oI, 199 Androst-5-en-17-ol-3-one, 32 Androst-l-en-3-one, 152 Androst-4-en-3 -one, 152 5a-Androst-8-en-l 1-one, 189 5 -Androst-8(14)-en-15-0ne, 155 Anhydrous hydrogen fluoride, 425 Aqueous hydrogen fluoride, 435 Argentic picolinate, 241 17a-aza-D-homo-estrone methyl ether, 163... [Pg.259]

The characteristic color reaction of nicotinic acid with cyanogen bromide and /3-naphthylamine has been studied. The product is believed to be X-201. Argentic picolinate is a powerful oxidizing agent Thus, toluene is oxidized to benzyl alcohol, benzaldehyde, and benzoic acid in a stepwise, controllable manner. Primary alcohols were converted to aldehydes, secondary alcohols to ketones. Amines were oxidized to aldehydes or ketones in dimethylsulfoxide. [Pg.297]


See other pages where Argentic picolinate is mentioned: [Pg.109]    [Pg.11]    [Pg.11]    [Pg.179]    [Pg.192]    [Pg.339]    [Pg.281]    [Pg.330]    [Pg.64]    [Pg.349]    [Pg.33]    [Pg.37]    [Pg.109]    [Pg.139]    [Pg.147]    [Pg.150]    [Pg.152]    [Pg.392]    [Pg.402]    [Pg.405]    [Pg.69]    [Pg.79]    [Pg.201]    [Pg.118]    [Pg.442]    [Pg.442]    [Pg.318]   
See also in sourсe #XX -- [ Pg.241 ]




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