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Arbuzov-Michaelis-type rearrangement

Several promising processes are applied to the synthesis of 2-cyanoethylphosphonates, including, for example, the thermally induced Michaelis-Arbuzov-type rearrangement of diethyl 2-cyanoal-lylphosphite to diethyl 2-cyanoallylphosphonate (Scheme 6.30).- " -4 ... [Pg.275]

Scheme 1 Michaelis-Arbuzov (M-A) type of rearrangement in cationic polymerization of cyclic phosphonites. Scheme 1 Michaelis-Arbuzov (M-A) type of rearrangement in cationic polymerization of cyclic phosphonites.
These polymerizations proceed mostly by a Michaelis-Arbuzov (M-A) type of rearrangement (Scheme 1), involving cyclic phosphonium intermediates to produce poly-phosphinates or polyphosphonates (39). The presence of isomerized repeating units (40) was the result of the occurrence of side reactions. Sometimes the proportion of the isomerized units was higher than that of the normal units (39). ... [Pg.482]

See other pages where Arbuzov-Michaelis-type rearrangement is mentioned: [Pg.89]    [Pg.89]    [Pg.401]    [Pg.19]    [Pg.46]    [Pg.281]    [Pg.48]    [Pg.38]    [Pg.92]    [Pg.200]    [Pg.269]    [Pg.330]   
See also in sourсe #XX -- [ Pg.23 , Pg.326 ]



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Arbuzov rearrangement

Arbuzov-type rearrangements

Michaelis rearrangement

Michaelis-Arbuzov rearrangement

Rearrangements types

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