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Application of Deans Negative Eigenvalue Theorem to Aperiodic Polymers

Application of Dean s Negative Eigenvalue Theorem to Aperiodic Polymers.—The [Pg.64]

Assuming that some other convenient factorization is found in the form [Pg.64]

The representation of a polymer unit by one orbital is, of course, a rather crude approximation but calculations of this type49-50 may still throw light on the qualitative effects of aperiodicity. There seems to be, however, no difficulty in applying Dean s method in a more sophisticated way, namely substituting the matrix elements a and bt by Fock matrix blocks which could be taken from appropriate cluster calculations.51 [Pg.65]




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Aperiodic polymer

Aperiodicity

Application to Polymers

Deaning

Eigenvalue

Negative-eigenvalue theorem

Polymer negative

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