Apparent soil-water distribution coefficient

The advantage of using fugacity to calculate the equilibrium distribution coefficients becomes apparent when one compares the fugacity capacities of a HOP for several different phases. For example, consider a region of the unsaturated zone just below the ground surface where naphthalene is distributed between air, water, pure phase octanol, and soil at equilibrium. The fugacity capacities for these phases are repeated below in Eqs. (46)-(49) ... 

Adams, F., Burmester, C., Hue, N. V., and Long, F. L. (1980). Comparison of column-displacement and centrifuge methods for obtaining soil solution. Soil Sci. Soc. Am. J. 44, 733—735. Amoozegar-Fard, A. D., Nielsen, D. R., and Warrick, A. W. (1982). Soil solute concentration distribution for spatially varying pore water velocities and apparent diffusion coefficients. Soil Sci. Soc. Am.J. 46, 3—9. 

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