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Anomeric Couplings with Radical Acceptors

The intermolecular reactions between glycosidic free radicals and radical acceptors have provided a variety of novel structures inaccessible from other glycosidation pathways. Although the types of [Pg.320]

Zn/AcOH, reflux Zn//-PrOH, reflux BusSnH/CgHe, AIBN, reflux NaBH4/DMF, room temp. [Pg.321]

With all the anomeric activating groups useful in the generation of sugar-derived free radicals, glycosyl halides have been the most exploited. In the remainder of this section, various reactions involving glycosyl halides will be discussed. Additionally, the stereochemical consequences of these reactions will be analyzed. [Pg.322]

See other pages where Anomeric Couplings with Radical Acceptors is mentioned: [Pg.286]    [Pg.336]    [Pg.270]    [Pg.320]    [Pg.180]    [Pg.300]    [Pg.286]    [Pg.336]    [Pg.270]    [Pg.320]    [Pg.180]    [Pg.300]    [Pg.85]    [Pg.335]    [Pg.319]    [Pg.175]    [Pg.264]    [Pg.198]    [Pg.105]    [Pg.171]    [Pg.371]    [Pg.285]    [Pg.511]   


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Radical acceptors

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