Anisolesulfonyl Chloride

Related Reagents. Cyanamlde Guanidine 5 Methyl-Isothlonrea O-Methyllsourea IH Pyrazole 1 carboxamidine Hydrochloride. [Pg.18]

Handling, Storage, and Precautions corrosive and a lachry-mator. Store at room temperature under anhydrons conditions. Use In a fume hood. [Pg.18]

Solubility sol acetone, acetonitrile, FtOH, MeOH, dioxane, H2O. [Pg.18]

Form Supplied in solid widely available 98% pure. [Pg.18]

The addition of sulfonyl chlorides to alkenes In the presence of a catalytic amount of dIchlorotris(triphenylphosphIne) ruthenlum(II) affords 1 1 adducts. Under these reaction conditions It Is believed that sulfonyl radicals, which are confined to the coordination sphere of the metal complex, are involved. When the chiral phosphine (—)-DIOP ((2,3-0-isopropylidene)-2,3-dihydroxy-l,4-bis(diphenylphosphino)butane) is used as a ligand, the addition of 4-methoxybenzenesulfonyl chloride to styrene proceeds to provide the (R) isomer in 40% ee (eq 2). [Pg.18]

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